CobaltMaghrebV1, France, Analysis, bibRecord, 000484

Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

Identifieur interne : 000484 ( France/Analysis ); précédent : 000483; suivant : 000485

Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

Auteurs : Ouassini Benali-Baitich [France] ; Jean-Claude Daran [France] ; Yves Jeannin [France]

Source :

Journal of Organometallic Chemistry [ 0022-328X ] ; 1988.

RBID : ISTEX:64DF056EEEC6EA8C67575930158C30ABBFAF243D

Abstract

Reaction of C2Ph2 with [CoRu3(CO)13](PPN) affords the violet butterfly complex [CoRu3(μ-CO)2(CO)9(μ4η2-C2Ph2)](PPN), which crystallizes in triclinic space group P1, a 9.9840(8) Å, b 15.462(2) Å, c 19.572(3) Å, α 75.08(1)°, β 75.15(1)°, γ 87.85(3)°, V 2821(1) Å3, Z = 2. This study completes the series of structures of ruthenium-cobalt closo-M4C2 clusters.

Url:

https://api.istex.fr/document/64DF056EEEC6EA8C67575930158C30ABBFAF243D/fulltext/pdf

DOI: 10.1016/0022-328X(88)80193-1

Affiliations:

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ISTEX:64DF056EEEC6EA8C67575930158C30ABBFAF243D

Le document en format XML

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<front><div type="abstract" xml:lang="en">Reaction of C2Ph2 with [CoRu3(CO)13](PPN) affords the violet butterfly complex [CoRu3(μ-CO)2(CO)9(μ4η2-C2Ph2)](PPN), which crystallizes in triclinic space group P1, a 9.9840(8) Å, b 15.462(2) Å, c 19.572(3) Å, α 75.08(1)°, β 75.15(1)°, γ 87.85(3)°, V 2821(1) Å3, Z = 2. This study completes the series of structures of ruthenium-cobalt closo-M4C2 clusters.</div>
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Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri